Steam Thermodynamic Properties Calculator

STEAM THERMODYNAMIC PROPERTIES CALCULATOR SERIES OF INVESTIGATIONS

A given volume V of any ideal gas will have the same number of molecules. Gas properties are described in terms of state variables. The available functions are used to calculate the following properties in the single-phase state for temperatures 273.15 K steam thermodynamic properties calculator

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Model IFC-67 was tested and recognized as reliable for the calculation of the thermodynamic properties of water. This model was developed from a variety of experimental data available for H 2O, which is the most abundant chemical compound in nature and also the most often used reagent in the chemical industry. This paper presents the IAPWS-IF97 model in summarized form, and results obtained in applying it to the thermodynamic properties of water, including enthalpy, entropy, internal energy, and volume, in the states of compressed liquid, liquid-vapor equilibrium, and superheated steam, using calculation algorithms developed using common, universally available computational techniques.Keywords: thermodynamic properties, water and steam, calculation algorithmsIn the decade of the 1960's a model was formulated for the calculation of thermodynamic properties of water for industrial use, and was known as the IFC-67 model.

Steam Thermodynamic Properties Calculator Series Of Investigations

1:Where p s(T) represents the pressure at saturation, Region 4 in Fig. Table 1 summarizes some of the constants and properties used in the model.Table 1: Constants and properties of waterThe basic equation for Region 1 is an equation for the Gibbs free energy g, expressed in the adimensional form:N i, I i, J i= IAPWS coefficients and exponents included in Table 4.Equation 1 covers the following ranges of pressure and temperature in Region 1 as shown in Fig. Although the number of regions in the new model coincides with number in the previous model, some differences exist in the form in which the IFC-67 and IAPWS-IF97 models define the different regions. The new model was considered officially valid beginning in 1997, but due to the need for modifying existing design procedures and computational program codes, the IAPWS recommended an introductory period lasting at least until the end of 1999 during which IAPWS-IF97 was not officially mandated.The IAPWS-IF97 model consists of a group of equations for a group of five graphical regions representing thermodynamic properties of water, and valid in the following ranges:Figure 1 shows the ranges within which the equations are valid, and the regions into which each range has been divided. Each region requires the use of different equations, and furthermore the basic thermodynamic model chosen in relation to the interdependence of properties is not the same for each region.Based on these considerations, beginning in the decade of the 1980's, the International Association for the Properties of Water and Steam (IAPWS) decided to promote the development of a new series of investigations directed towards obtaining a new formulation for a model for the calculation of thermodynamic properties of water and steam, which was officially adopted in 1997 termed the 'IAPWS Industrial Formulation 1997 for the Thermodynamic Properties of Water and Steam', subsequently known as IAPWS-IF97. It required division of the area of validity of its equations into five different regions due to the complexity of the behavior of the thermodynamic properties of water.

1.All the thermodynamic properties can be derived from equation 7 according to the equations summarized in Tables 8 and 9.Table 8: Thermodynamic relations with the Helmholz free energy f and the corresponding adimensional equations.Table 9: Derivatives of f used in the equations of Table 8.Table 10: IAPWS coefficients and exponents of equation 7.Region 4 represents a saturation curve. Thus, for example:The limit between regions 2 and 3 is given by a quadratic equation for the pressure as a function of the temperature:N i= IAPWS coefficients included in Table 7.Table 7: IAPWS coefficients of equations 8 and 9.This equation can also be expressed in explicit form as the temperature as a function of the pressure in the following form:The basic equation for Region 3 differs from those of Regions 1 and 2 since it is an equation for the Helmholtz free energy f, which, expressed in adimensional form is:N i, I i, J i= IAPWS coefficients and exponents included in Table 10.The equation for Region 3 covers the following ranges of temperature and pressure as shown in Fig. In this case it must be considered that the equations of Table 2 must be applied both to the ideal part and to the residual part of the model. 1: 273.15 K < T < 623.15All the thermodynamic properties for this region can be derived from equations 2, 3, and 4 following the equations outlined in Tables 1 and 2. The equation is expressed in adimensional form, and is separated into two parts, one for the ideal gas g 0 and the other residual g r, that is:The equations for the ideal gas and for the residual part are:N i 0, J i 0 = IAPWS coefficients and exponents included in Table 5.Table 5: IAPWS coefficients and exponents of equation 3.N i, I i, J i= IAPWS coefficients and exponents included in Table 6.Table 6: IAPWS coefficients and exponents of equation 4.Equation 2 covers the following ranges of pressure and temperature of Region 2 as shown Fig. Table 4: IAPWS coefficients and exponents of equation 1.For Region 2 the model is also based on Gibbs free energy g.